Projects
Studies on the human Pgp folding
PI Daniel dos Santos
CBIOS Team member
Patrícia Dias de Mendonça Rijo
From 2022 to 2023
Description
Overexpression of P-glycoprotein (Pgp/ABCB1) in cancer is a marker of overall poor chemotherapy response and prognosis. This computational project builds on previous studies lead by the PI and Co-PI on multidrug resistance (MDR) in cancer by using computational models and simulations for gaining information about the inner dynamics, structural features and drug-Pgp interaction and mode of action.
The human Pgp conformations deposited recently on the Protein Data Bank revealed a new inward facing conformation that may represent either the closing of a gate region or an artifact derived from lateral compression in a too small size nanodisc, used to stabilize the transporter. Using a simpler model, we have done preliminary investigations pointing for the presence of an artifact in the experimental protocol (DOI:10.1101/692988).
However, this hypothesis can only be tested and settled using molecular dynamics simulations at very long time scales with complete atomistic description of the biochemical system, impossible to match using in-house resources. Knowing if there is an artifact on the human structures or if this new structures correspond to a yet to be confirmed meta-stable intermediary state is of capital importance since further computational studies of Pgp can only produce reliable information when using Pgp structures representative of its correct native fold.
Outputs
- Bonito, C. A.; Ferreira, R. J.; Ferreira, M.-José. U.; Durães, F.; Sousa, E.; Gillet, J.-P.; Cordeiro, M. N. D. S.; dos Santos, D. J. V. A. Probing the Allosteric Modulation of P-Glycoprotein: A Medicinal Chemistry Approach Toward the Identification of Noncompetitive P-Gp Inhibitors. ACS Omega 2023, 8 (12), 11281–11287. https://doi.org/10.1021/acsomega.2c08273.
- Bonito, C. A.; Ferreira, R. J.; Ferreira, M.-J. U.; Gillet, J.-P.; Cordeiro, M. N. D. S.; dos Santos, D. J. V. A. Long-Range Communication between Transmembrane- and Nucleotide-Binding Domains Does Not Depend on Drug Binding to Mutant P-Glycoprotein. Journal of Biomolecular Structure and Dynamics 2023, 0 (0), 1–10. https://doi.org/10.1080/07391102.2023.2181633 .
Funding
FCT Advanced Computing Project, reference 2021.09821.CPCA